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Synthetic nootropics & research compounds

Methylene Blue

Methylthioninium chloride / methylene blue

Methylene Blue (methylthioninium chloride) is a redox-active thiazine dye. In U.S. labeling, its intravenous presentation is prescription medicine for acquired methemoglobinemia, not a standard supplement. A 26-person randomized fMRI study reported acute attention- and memory-related findings after a low oral amount, but this does not establish that unsupervised nootropic use is safe or effective. Its label has boxed interaction warnings and also carries G6PD, pregnancy, route, and product-quality concerns.

Legal CautionMedication Interaction RiskCellular SupportMitochondrial SupportAntioxidant PathwaysIsolated CompoundSynthetic
Updated August 2026/5 min read/6 citations
Reviewed by the NootropicsIndex editorial team.Method: prioritize cited human research and official safety or regulatory sources; compare retailer-listed prices without endorsing products.Affiliate disclosure
01

What is it?

Prescription redox drug, not an ordinary supplement

1

Methylene Blue is methylthioninium chloride, a redox-active thiazine dye and U.S. prescription IV medicine whose label has an indication for acquired methemoglobinemia. Online nootropic drops and powders are not equivalent to labeled injectable medicine.

The cognition signal is small and insufficient for self-use

3

A randomized, double-blind fMRI trial enrolled 26 healthy adults and compared a single oral methylene-blue administration with placebo. It reported task-related brain-signal changes and a memory-retrieval finding, but was small, acute, and not a consumer safety or use study.

Alzheimer research does not validate supplement marketing

5

Leuco-methylthioninium and hydromethylthionine studies are clinical drug-development programs in Alzheimer populations. They do not validate consumer claims about cognitive decline or healthy cognition.

02

Names, aliases and forms

Chemical Namesmethylthioninium chloride; phenothiazin-5-ium dye
Common Namemethylene blue
Active Constituentredox-active methylthioninium
Pubchem Cid6099
Molecular FormulaC16H18ClN3S
InchikeyCXKWCBBOMKCUKX-UHFFFAOYSA-M
03

Mechanisms of action

Mitochondrial/redox mechanisms cut both ways

6

Methylene Blue can participate in redox cycling and has mitochondrial and nitric-oxide/cGMP-related mechanism discussions. Mechanistic plausibility is not safety: the same drug-like activity is part of why dose, product grade, route, and medication context matter.

04

Potential effects and evidence map

Methylene Blue has a U.S.-labeled IV indication for acquired methemoglobinemia and mechanistic relevance to mitochondrial/redox biology. The nootropic evidence is much thinner: a 26-person randomized fMRI study reported neural and task-related findings after low-dose oral administration. That finding does not establish unsupervised nootropic use. Safety dominates this profile: the U.S. label carries a boxed warning for serotonin syndrome with serotonergic drugs and opioids and has G6PD, pregnancy, hemolysis, renal/hepatic, and route-specific precautions.

Effect domainMagnitudeGrade
Focus / attention3
AcuteConfidence: Low

A small randomized fMRI study reported attention-related neural/task effects, but this is not enough to establish unsupervised nootropic self-use.

Note Do not generalize one 26-person study into a routine focus protocol.

1/5
C
Memory / learning3
AcuteConfidence: Low

A small human study suggests short-term memory-related effects, but replication and safety context are insufficient for nootropic recommendations.

Note Memory signals are outweighed by drug-like risk for unsupervised users.

1/5
C
Mental energy / wakefulness1
UnknownConfidence: Low

Methylene Blue is not an established wakefulness, stimulant, or productivity supplement.

Note Redox/mitochondrial framing is not an energy-use proof point.

0/5
E
Cellular / long-term brain support5
CumulativeConfidence: Low

Methylthioninium derivatives have Alzheimer and tau-aggregation research context, but this does not validate consumer brain-health claims.

Note Alzheimer trials involve drug-development products and clinical populations.

1/5
D
Mood / wellbeing1
UnknownConfidence: Low

No reliable human mood or wellbeing benefit is established for Methylene Blue as a consumer nootropic.

Note Avoid serotonergic stacking because the safety issue is in the opposite direction.

0/5
E
05

Dose/listing context

Consumer use1No validated consumer dose

The 1 mg/kg IV regimen in the U.S. prescription label applies to its labeled clinical indication and care setting. It is not an oral nootropic dose and it does not apply to drops, aquarium products, laboratory dyes, or compounded products.

06

Safety, side effects and risk profile

Interaction risk1
Confidence: High

The U.S. prescription label carries its highest-level warning against combining methylene blue with serotonergic drugs or opioids because serotonin syndrome can be serious or fatal.

Note The label specifically names SSRIs, SNRIs, MAOIs, opioids, bupropion, buspirone, clomipramine, mirtazapine, linezolid, and dextromethorphan; medication review is essential.

5/5
A
Legal / regulatory risk1
Confidence: High

In the United States, methylene blue injection is a prescription drug for acquired methemoglobinemia, not an FDA-approved nootropic supplement.

Note Aquarium, laboratory, textile, or reagent-grade products are not ingestion-grade medicines.

5/5
A
Liver / kidney caution1
Confidence: Medium

DailyMed includes renal and hepatic impairment cautions and reports hemolysis/hyperbilirubinemia concerns, especially in vulnerable patients.

Note Also screen for G6PD deficiency because response may be reduced and hemolysis risk increased.

4/5
B
Pregnancy / lactation caution1
Confidence: High

The U.S. label says methylene blue may cause fetal harm and directs interruption of breastfeeding for up to 8 days after labeled clinical use.

Note Pregnancy and lactation are incompatible with casual nootropic use.

5/5
A
Headache / dizziness1
Confidence: Medium

Adverse effects can include pain, headache, dizziness, nausea, vomiting, confusion, sweating, hypertension, and discoloration of urine or skin.

Note Blue discoloration can also interfere with pulse oximetry readings.

2/5
B
Evidence uncertainty1
Confidence: Medium

Consumer products vary by salt form, concentration, purity, route, contaminants, and whether they are pharmaceutical, laboratory, aquarium, or compounded preparations.

Note The product-grade problem is central for this compound.

4/5
B
Medical screens1

The label discusses G6PD deficiency, hemolysis, hyperbilirubinemia, renal impairment, hepatic impairment, and interference with pulse oximetry. These are not normal supplement caveats; they require medical context.

Pregnancy / lactation1

The U.S. prescription label says methylene blue may cause fetal harm and directs interruption of breastfeeding for up to 8 days after labeled clinical use. These risks make casual nootropic use inappropriate in pregnancy or lactation.

07

Interactions and cautions

Boxed warning1

The U.S. prescription label warns that methylene blue can cause serious or fatal serotonin syndrome with serotonergic drugs and opioids. It specifically names SSRIs, SNRIs, MAOIs, opioids, bupropion, buspirone, clomipramine, mirtazapine, linezolid, and dextromethorphan.

09

Practical buying and quality notes

  • Avoid aquarium, textile, laboratory, reagent, or unclear-grade methylene blue for ingestion. Labels should not be trusted unless they clearly identify pharmaceutical-grade source, concentration, contaminants, batch testing, route, and medical-use context.1
  • Do not combine methylene blue with serotonergic medicines, opioids, or dextromethorphan without a prescriber or pharmacist who can assess the interaction risk. Its prescription label carries a boxed warning for this issue.1
10

FAQ

Is Methylene Blue a nootropic?

3

It has a small human attention/memory signal, but it is better regarded as a drug-like redox compound with critical safety constraints, not a routine nootropic supplement.

Is there a consumer nootropic dose?

1

No validated consumer nootropic dose is established. The U.S. label describes IV administration for its specified clinical indication, not an oral nootropic regimen or a conversion for drops, aquarium products, laboratory dyes, or compounded products.

Who should avoid unsupervised Methylene Blue?

1

Anyone using SSRIs, SNRIs, MAOIs, opioids, serotonergic supplements, dextromethorphan, tramadol, linezolid, or complex medications; anyone with G6PD deficiency, pregnancy, breastfeeding, kidney/liver disease, or unclear product grade; and anyone considering nonpharmaceutical products.

11

References

  1. DailyMed. PROVAYBLUE (methylene blue) injection prescribing information, updated May 2025. Accessed 2026-08-21.
  2. PubChem. Methylene Blue, CID 6099. Accessed 2026-06-30.
  3. Multimodal Randomized Functional MR Imaging of the Effects of Methylene Blue in the Human Brain. Radiology. 2016;281(2):516-526.
  4. Potential of Low Dose Leuco-Methylthioninium Bis(Hydromethanesulphonate) Monotherapy for Treatment of Mild Alzheimer's Disease. Journal of Alzheimer's Disease. 2018;61(1):435-457.
  5. Oral Tau Aggregation Inhibitor for Alzheimer's Disease: Design, Progress and Basis for Selection of the 16 mg/day Dose in a Phase 3 Trial. Journal of Prevention of Alzheimer's Disease. 2022;9(1):111-122.
  6. Methylene blue and Alzheimer's disease. Biochemical Pharmacology. 2009;78(8):927-932.
Note

This page is informational and summarizes available evidence. It is not medical advice, a recommendation, or a substitute for guidance from a qualified clinician.